Database of luminescent Minerals


SODALITE


Chemical Formula: Na8Al6Si6O24Cl2

Familly: Silicates

Status: IMA-GP

Crystal System: Isometric

Mineral for Display: Yes

Associated names (luminescent varieties, discredited names, synonymes etc.):  hackmanite

Luminescence:


UV Type Main color Intensity Observation Frequency
Long Waves (365nm):      Orange Very StrongOften
Short Waves (254 nm):      Yellowish White Medium
Other colors LW:                              
Yellowish White , Orangy yellow , Red , Violet red , Violet Pink , Pink ,
Other colors SW:                         
Orange , Violet red , Violet Pink , Salmon pink , Green ,

Daylight Picture


Sodalite
Ilimaussaq Complex, Greenland;
Courtesy MinerShop.com

Long Waves Picture (365nm)


Sodalite, UV LW orange;
Ilimaussaq Complex, Greenland;
Courtesy MinerShop.com

Short Waves Pictures (254nm)


Sodalite, UV SW orange red ;
Ilimaussaq Complex, Greenland;
Courtesy MinerShop.com

 

Galerie de photos:

            ...

     To the gallery (7 images in the gallery)


Phosphorescence (in the common meaning of the term) seen by naked eye:


UV Type Color Intensity Observation Frequency
Long Wave (365nm): Bluish White StrongOften
Short Waves (254 nm): Bluish White Very StrongOften
 

Ténébrescence: OUI




Sodalite, left before and right after exposition to SW (tenebrescence);
Ilimaussaq Complex, Greenland;
Courtesy MinerShop.com

Thermoluminescence: Yes


Comments:


HACKMANITE : strongly tenebrescent variety of sodalite
From Mont Saint-Hillaire, certain sodalite fluoresces yellow. The response is seen under SW and MW, weaker under LW. Build-up is slow but becomes bright.


Main Activator(s) and spectrum:


Most Common Activator: S2-

Other activators:            (UO2)2+ (Uranyl ion) as impurities , Fe3+ , Mn2+ ,

Peaks in the spectrum (nm):

S2- : 587, 608, 628, 653, 677, 707, 732nm

Fe3+? repl. Al3+ : 687-720nm 

(UO2)2+ : 495, 515, 537nm

Mn2+ repl. Na+ : 650nm


Spectrum: Michael Gaft, Petah Tikva, Israel. Plot: Institute of Mineralogy, University of Vienna, Austria, with permission of the authors.

      ...

  To the spectrum gallery (2 spectra in the gallery)


Comments on activators and spectra:


Some time Green Luminescence due to uranium impurities;

 

Cathodoluminescence: intensive greenish-blue or yellow-green or orange.

 

The photoluminescence and excitation spectra of sodalites from Greenland, Canada and Xinjiang (China) are observed at 300 and 10 K in detail. The features of the emission and excitation spectra of the orange-yellow fluorescence of these sodalites are independent of the locality. The emission spectra at 300 and 10 K consist of a broad band with a series of peaks and a maximum peak at 648 and 645.9 nm, respectively. The excitation spectra obtained by monitoring the orange-yellow fluorescence at 300 and 10 K consist of a main band with a peak at 392 nm. The luminescence efficiency of the heat-treated sodalite from Xinjiang is about seven times as high as that of untreated natural sodalite. The emission spectrum of the S2 − center in sodalite at 10 K consists of a band with a clearly resolved structure with a series of maxima spaced about 560 cm−1 (20–25 nm) apart. Each narrow band at 10 K shows a fine structure consisting of a small peak due to the stretching vibration of the isotopic species of 32S34S−, a main peak due to that of the isotopic species of 32S2 − and five peaks due to phonon sidebands of the main peak. (see Aierken Sidike, Alifu Sawuti, Xiang-Ming Wang, Heng-Jiang Zhu, S. Kobayashi, I. Kusachi, N. Yamashita, Fine structure in photoluminescence spectrum of S2 center in sodalite, Physics and Chemistry of Minerals, September 2007, Volume 34, Issue 7, pp 477–484 )

The emission and excitation spectra of yellow luminescence due to S2 in scapolites (from Canada and  from an unknown locality) were observed at 300, 80 and 10 K. Emission and excitation bands at 10 K showed vibronic structures with a series of maxima spaced 15–30 and 5–9 nm, respectively. The relative efficiency of yellow luminescence from scapolite #2 was increased up to 117 times by heat treatment at 1,000°C for 2 h in air. The enhancement of yellow luminescence by heat treatment was ascribed to the alteration of SO32− and SO4 2− to S2 in scapolite. (see Aierken Sidike, I. Kusachi, S. Kobayashi, K. Atobe, N. Yamashita, Photoluminescence spectra of S2 center in natural and heat-treated scapolites, Physics and Chemistry of Minerals, April 2008, Volume 35, Issue 3, pp 137–145 )

 


Best Locality for luminescence(*):


(*)Data are not exhaustive and are limited to the most important localities for fluorescence


Bibliographical Reference for luminescence:



Luminescence Reference on internet:



Mineralogical Reference on internet:


  http://www.mindat.org/show.php?name=Sodalite

  http://webmineral.com/data/Sodalite.shtml

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