ARAGONITE
Scheikundige formule: CaCO3
Familie: Carbonaten
Status: IMA-GP
Kristal Systeem: Orthorhombisch
Mineraal om tentoon te stellen: Ja
Fluorescerende variëteiten:
flos ferri, nicholsonite, strontio-aragonite, mossottite, tarnowitzite, ammolite, septaria, parel, ktypeite, Erzbergite,
Fluorescentie:
UV Type |
Kleur |
Intensiteit |
Frequentie van de observatie |
Lange Golven (365nm): | Gelig wit | Sterk | Dikwijls |
Midden Golven (320 nm): | Roze | | | Korte Golven(254 nm): | Blauw wit | Middelmatig | Dikwijls | | | | |
Andere kleuren lange golven: | Witte , Blauw wit , Roos wit , Oranje , Oranje rood (Zalmkleurig) , Rood , Violet rood , Violet roos , Roze , Zalm roos , Blauw , Groen wit , |
Andere kleuren Midden golven: | Witte , Blauw wit , Gelig wit , Roos wit , Bleek geel , Oranje rood (Zalmkleurig) , Rood , Violet rood , Violet roos , Zalm roos , Groen wit , Geelachtig , |
Andere kleuren korte golven: | Witte , Blauw wit , Gelig wit , Roos wit , Bleek geel , Oranje , Oranje rood (Zalmkleurig) , Rood , Violet rood , Violet roos , Roze , Zalm roos , Geel groen , Groen , Groen wit , Geelachtig , |
Lange golf foto (365nm)
ARAGONITE, Sicily, Italy.
OL (365 nm)
Col. G.Barmarin; Photo: G. Barmarin
Korte golf foto (254nm)
ARAGONITE, Sicily, Italy.
OC (254 nm)
Col. G.Barmarin; Photo: G. Barmarin
Foto galerij:
...
Naar de volledige galerij (8 beelden in totaal)
Fosforescentie (in de algemene betekenis) zien met het blote oog:
UV Type |
Kleur |
Intensity |
Observation Frequency |
Lange golven(365nm): | Groen wit | Sterk | Soms |
Midden Golven (320 nm): | Groen wit | Sterk | Soms | Korte golven (254 nm): | Groen wit | Sterk | Soms |
Thermoluminescencie: Ja
Commentaar:
- Nicholsonite (Zincian Aragonite): OL: jaune-orangé; OC: blanc-bleuté, crème;
- Strontio-aragonite: OL: rouge-orangé, rose; OC: rose, blanc;
- Tarnowitzite (aragonite plombifère): OL:orange, jaune, crème, vert; OC: jaune, crème;
Kunz and Baskerville noted that aragonite fluoresces often strongly during their memorable investigation of 13000 mineral specimens in 1903.
Activator en spectrum:
Voornaamste Activator: Mn2+
Andere activatoren: (UO2)2+ (Uranyl ion) (onzuiverheden) , Onzuiverheden organisch materiaal , Ce3+ , Sm3+ , Eu3+ , Dy3+ , Centra als gevolg van de effecten van straling ,
Pieks in het spectrum (nm):
Sm3+ repl. Ca2+ : 603, 640nm
Mn2+ : broad band at 630nm (120nm half-width)
Dy3+ : 482, 486, 578, 579nm
Radiation induced center : 580nm (very short decay time of approximately 20 ns)
Spectrum: Michael Gaft, Petah Tikva, Israel. Plot: Institute of Mineralogy, University of Vienna, Austria, with permission of the authors.
...
Vers la galerie de spectres (3 spectres au total)
Commentaar over activators en spectra:
Fluo green: due to U in traces;
Activators: Mn2+, Sm3+, Dy3+ (Gaft)
The broad luminescence band peaking at 580 nm with very short decay time of approximately 20 ns, could by analogy with Terlingua-type calcite may be preliminarily ascribed to radiation induced luminescence center. (Gaft)
Under cw laser excitation at 532 and 780nm several bands and narrow lines have been found in visible and IR parts of the spectrum. Evidently they may be connected with another type of Mn2+, trivalent REE, such as Sm3+, Eu3+ and different types of Nd3+ centers. The origin of the broad band peaking at approximately 700 nm needs further study.
The frequent occurrence of slight amounts of Strontium in aragonite was known during the time of Becquerel and he ascribed the luminescence to the presence of strontium. Later, Nichols confirmed the idea. Hence the name strontioaragonite for some specimen of very bright red fluorescing aragonite.
Actually, strontium is not considered anymore as the activator responsable for the red fluorescence of aragonite and Mn and REE are considered as the principal activators of this red fluorescence.
Beste vindplaats voor fluorescentie(*):
- Strontio-aragonite: red SW and LW, Boccheggiano mines, Montieri, Grosseto Province, Tuscany, Italy;
- Aragonite fluo pink/salmon LW, white SW : Sulphur Mine near Agrigento, Agrigento Province, Sicily, Italy;
- Giumentaro Mine (Capodarso Mine), Capodarso, Enna (Castrogiovanni), Enna Province, Sicily, Italy;
- Cozzo Disi Mine, Casteltermini, Agrigento Province, Sicily, Italy;
- Nicholsonite: fluo and phospho white SW & cream LW, Zinc Mine Friedenville, Friedensville, Saucon Valley, Upper Saucon Township, Lehigh Co., Pennsylvania, USA
- Tarnowitzite:yellowish-white, strongest SW or red SW: Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia;
- Tarnowitzite: Touissit, Touissit District, Jerada Province, Oriental Region, Morocco ( Straw-yellow fluorescence SW+LW);
- Aragon de Molina, Spain (Twinned xls agregated in balls);
- Tazouta, Sefrou, Sefrou Province, Fès-Boulemane Region, Morocco (Twinned xls agregated in balls, dull green SW);
- Chihuahua, Mexico (bright green SW);
- Gallo river, Molina de Aragón, Guadalajara, Castile-La Mancha, Spain (dull white SW);
- Pantoja, Toledo, Castile-La Mancha, Spain (Acicular Aragonite bright blue-white LW);
- Great Southern Mine, Red Picacho District, Wickenburg area, Yavapai Co., Arizona, USA;
- Copper Canyon, Camp Verde, Camp Verde District, Yavapai Co., Arizona, USA (aragonite pseudomorph after glauberite, cream-yellow LW, MW & SW);
- Bisbee, Warren District, Mule Mts, Cochise Co., Arizona, USA (Patches of bright green fluorescence under SW & patches of bright creamy white fluo LW);
- Long Lake Zinc Mine, Olden Township, Frontenac Co., Ontario, Canada (fluo blue SW in red fluo calcite);
(*)Gegevens zijn niet exhaustieve, ze zijn beperkt tot de meest belangrijke plaatsen voor fluorescentie
Referentie voor fluorescentie:
- The Henkel Glossary of Fluorescent Minerals, Dr. Gerhard Henkel, Published by the FMS, 1989 ,
- Fluorescence: Gems and Minerals Under Ultraviolet Light, Manuel Robbins, 1994, Geoscience Press, ISBN 0-945005-13-X ,
- The World of Fluorescent Minerals, Stuart Schneider, Schiffer Publishing, 2006, ISBN 0-7643-2544-2 ,
- Luminescence Spectroscopy of Minerals and Materials, M. Gaft, R. Reisfeld, G. Panczer, Springer Editor, ISBN: 10 3-540-21918-8 ,
- Luminescent Spectra of Minerals, Boris S. Gorobets and Alexandre A. Rogojine, Moscow, 2002 ,
- Handbook of Fluorescent Gems and Minerals, a practical guide for the gem and mineral collector, Jack de Ment, 1949 ,
Referentie voor luminenscentie op het internet:
- MONT-SAINT-HILAIRE, History, Geology, Mineralogy, Laszlo HORVATH, The Canadian Mineralogist, Special Publication 14, 2019
Images:
- Pantoja, Toledo, Spain (Acicular Aragonite bright blue-white LW): http://www.mindat.org/photo-100547.html
- Great Southern Mine, Arizona, USA (with calcite & fluorite): http://www.mindat.org/photo-67554.html
- Great Southern Mine, Arizona, USA (with calcite & fluorite, details): http://www.mindat.org/photo-67557.html
- Agrigento, Agrigento Province, Sicily, Italy: http://www.mindat.org/photo-415916.html
- Giumentaro Mine, Enna Province, Sicily, Italy: https://www.mindat.org/photo-504841.html
- Bisbee, Arizona, USA: http://www.mindat.org/photo-505652.html
- Long Lake Zinc Mine, Ontario, Canada:
- Nicholsonite: Zinc Mine Friedenville, Pennsylvania, USA (SW): http://www.mindat.org/photo-573241.html
- Nicholsonite: Zinc Mine Friedenville, Pennsylvania, USA (LW): http://www.mindat.org/photo-573242.html
- Nicholsonite: Zinc Mine Friedenville, Pennsylvania, USA (SW): http://www.mindat.org/photo-573244.html
- Nicholsonite: Zinc Mine Friedenville, Pennsylvania, USA (LW): http://www.mindat.org/photo-573245.html
Mineralogische Referentie op het internet:
http://www.mindat.org/show.php?name=Aragonite
http://webmineral.com/data/Aragonite.shtml
Onderzoek op Internet:
Beelden op 'Google Image'
Dokumenten in het Nederlands op Google
Dokumenten in alle talen op Google
Onderzoek op Wikipédia
Note: While all due attention has been paid to the implementation of the database, it may contain errors and/or accidental omissions. By nature, the database will always be incomplete because science always evolves according to new analysis.
A request providing no result means only that no such reference exists in the database, but it does not mean that what you are looking for does not exist, just not to our knowledge. If you think you have found an error or omission, please let us know
via the contact page being sure to cite the source of information.